THE INHIBITORATION OF OXIDATION REACTIONS OF ORGANIC SUBSTANCES BY TIOSEMICARBAZONE

Authors

  • L. R. Vardanian YSU, Goris SU, Armenia
  • R. L. Vardanian YSU, Goris SU, Armenia
  • V. S. Haroutunian YSU, Goris SU, Armenia
  • T. V. Ghochikian YSU, Goris SU, Armenia
  • A. A. Avetisian YSU, Goris SU, Armenia

DOI:

https://doi.org/10.46991/PYSUB.2001.35.1.079

Abstract

It is studied that the TSK influence of cumene, CHP and OS-20 on initiation on the quickness of oxidation rate of reactions is studied. It is shown that in any case TSK displays an inhibitorating character. Kinetic parameters characterizing the inhibitor are measured. During the oxidation of cumene in the reaction RO2 + In→ROOH +In the temperature dependence of velocity constant is determined as: k7 = 4.49·108 exp(-5300/RT) L/mol·s.

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Published

2001-03-16

Issue

Vol. 35 No. 1 (194) (2001)

Section

Chemistry

License

Copyright (c) 2001 Proceedings of the YSU

Creative Commons License

This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.

How to Cite

“THE INHIBITORATION OF OXIDATION REACTIONS OF ORGANIC SUBSTANCES BY TIOSEMICARBAZONE”. 2001. Proceedings of the YSU B: Chemical and Biological Sciences 35 (1 (194): 79-85. https://doi.org/10.46991/PYSUB.2001.35.1.079.