QUANTITATIVE CHARACTERIZATION OF THE REACTIONARY MEDIUM BY MEANS OF SEMIEMPIRICAL CORRELATION EQUATIONS

Authors

  • G. S. Simonian Chair of Physical and Colloids Chemistry, YSU, Armenia

DOI:

https://doi.org/10.46991/PYSUB.2002.36.3.045

Abstract

Literature data concerning empirical and semiempirical correlation equations and parameters obtained by kinetic, spectroscopic (UV, IR, NMR) and thermodynamic methods, which characterize the solvent and which are being used to discuss different reaction series have been analysed. Correlations between considered parameters have been established.

In the present communication the application of multiparametric correlation equations to analyse radical and nonradical reactions has been discussed. It has been shown that parameters characterizing the solvents may be used to examine the action of specific as well as nonspecific solvation’s effect, but also to classify the solvents.

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Published

2002-09-20

Issue

Vol. 36 No. 3 (199) (2002)

Section

Chemistry

License

Copyright (c) 2002 Proceedings of the YSU

Creative Commons License

This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.

How to Cite

“QUANTITATIVE CHARACTERIZATION OF THE REACTIONARY MEDIUM BY MEANS OF SEMIEMPIRICAL CORRELATION EQUATIONS”. 2002. Proceedings of the YSU B: Chemical and Biological Sciences 36 (3 (199): 45-53. https://doi.org/10.46991/PYSUB.2002.36.3.045.