STUDY OF CHROMIUM(VI) INTERACTION WITH 2-(3-(AZEPAN-1-YL)-2-HYDROXYPROPYLTHIO)ACETIC ACID

Authors

  • H.H. Darbinyan Chair of Inorganic and Analytical Chemistry, YSU, Armenia
  • A.S. Galstyan Chair of Organic Chemistry, YSU, Armenia
  • H.G. Khachatryan Chair of Inorganic and Analytic Chemistry, YSU, Armenia

DOI:

https://doi.org/10.46991/PYSU:B/2014.47.3.013-017

Keywords:

ion-chromatographic determination, amperometric titration method, spectrophotometric titration method

Abstract

The interaction of chromium(VI) with 2-(3-(azepan-1-yl)-2-hydroxypropilthio) acetic acid has been studied by means of potentiometric, amperometric and spectrophotometric titration methods. The titration is possible to carry out in the acidity range $3.0-7.0~mol / L$ by sulfuric acid. Molar ratio of the reacting agents is [Cr(VI)] : [Reagent] $= 2 : 3$. Conformity to the Beer’s law is preserved when $8.3\cdot10^6-2.0\cdot10^3~mol / L$ at $E=+0.2~V$ and when $2.0\cdot10^5-2.0\cdot10^3~mol / L$ at $E =+1.2~V$ chromium(VI) solutions were titrated. The technique elaborated has been approved during the analysis of standard chromium-containing ore with standard relative deviation 0.61% . Possible scheme describing the interaction of chromium(VI) with the reagent has been suggested. 

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Published

2013-11-15

How to Cite

Darbinyan, H.H., A.S. Galstyan, and H.G. Khachatryan. 2013. “STUDY OF CHROMIUM(VI) INTERACTION WITH 2-(3-(AZEPAN-1-YL)-2-HYDROXYPROPYLTHIO)ACETIC ACID”. Proceedings of the YSU B: Chemical and Biological Sciences 47 (3 (232):13-17. https://doi.org/10.46991/PYSU:B/2014.47.3.013-017.

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Section

Chemistry