CHARGE COMPONENTS OF INDUCTIVE EFFECT OF ALKYL GROUPS AND THEIR INFLUENCE ON THE CHEMOSELECTIVITY OF ALCOHOLS BENZOYLATION

Authors

  • K.H. Petrosyan Institute of Organic Chemistry of Scientific-Technological Center of Organic and Pharmaceutical Chemistry, NAS RA

DOI:

https://doi.org/10.46991/PYSU:B/2016.50.3.019

Keywords:

electronegativity, chemoselectivity of molecules, acid of Pauling, base of Pauling

Abstract

The inductive effect of alkyl groups of alcohols is an additive quality, which arises because of the differences in electronegativities of atoms of hydrogen, carbon, and oxygen in the molecule of alcohol are provided. Thanks to that a negative charge is formed on carbon atoms of the C–H bond, and a positive charge on carbon atoms of C–O bond. We show that these charges are equivalent to the natural forces of affinity, which cause the chemoselectivity of molecules.

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Published

2016-11-21

How to Cite

Petrosyan, K.H. 2016. “CHARGE COMPONENTS OF INDUCTIVE EFFECT OF ALKYL GROUPS AND THEIR INFLUENCE ON THE CHEMOSELECTIVITY OF ALCOHOLS BENZOYLATION”. Proceedings of the YSU B: Chemical and Biological Sciences 50 (3 (241):19-24. https://doi.org/10.46991/PYSU:B/2016.50.3.019.

Issue

Vol. 50 No. 3 (241) (2016)

Section

Chemistry

License

Copyright (c) 2016 Proceedings of the YSU

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