INVESTIGATION OF THE INTERMOLECULAR INTERACTION OF VITAMIN E WITH DIMETHYL-, DIETHYLSULPHOXIDS BY IR SPECTROSCOPY

Authors

  • L. G. Melik-Ohanjanian Chair of Physical and Colloids Chemistry, YSU, Armenia
  • L. A. Nersesian Chair of Physical and Colloids Chemistry, YSU, Armenia
  • Sh. A. Markarian Chair of Physical and Colloids Chemistry, YSU, Armenia

DOI:

https://doi.org/10.46991/PYSU:B/2006.40.1.074

Keywords:

vitamin E, dimethylsulphoxide, diethylsulphoxide, IR spectrums, complex-formation

Abstract

Absorbed IR spectrums of vitamin E in presence of dimethyl-, diethylsulphoxides in CCl4 have been investigated. It has been shown that complex-formation of vitamin E with sulphoxides is the result of formation of hydrogen bond between hydrogen of vitamin E hydroxyl group and oxygen of the sulphoxides S=0 group. It have been established the equilibrium constants (K) of vitamin E complexes with dimethylsulphoxide (K=13.2 L/mol) and diethylsulphoxide (K=18.2 L/mol) at 23℃.

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Published

2006-03-07

How to Cite

Melik-Ohanjanian, L. G., L. A. Nersesian, and Sh. A. Markarian. 2006. “INVESTIGATION OF THE INTERMOLECULAR INTERACTION OF VITAMIN E WITH DIMETHYL-, DIETHYLSULPHOXIDS BY IR SPECTROSCOPY”. Proceedings of the YSU B: Chemical and Biological Sciences 40 (1 (209):74-79. https://doi.org/10.46991/PYSU:B/2006.40.1.074.

Issue

Vol. 40 No. 1 (209) (2006)

Section

Chemistry

License

Copyright (c) 2006 Proceedings of the YSU

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This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.