THE ACTION OF UNSATURATED CYANOLACTON ON Η2Ο2+ΗΟΟ− REACTION RATE IN ABSENCE AND PRESENCE OF MICELLES

Authors

  • N. M. Beylerian Faculty of Chemistry, YSU, Armenia
  • M. Z. Asaturyan Faculty of Chemistry, YSU, Armenia
  • P. G. Minasyan Faculty of Chemistry, YSU, Armenia

DOI:

https://doi.org/10.46991/PYSUB.2010.44.1.012

Keywords:

2-cyano-3,4,4-trimethyl-2-butene-4-olid, lacton, micellar systems, reaction rate

Abstract

Using gasometric method at 303 K the action of 2-cyano-3,4,4-trimethyl-2-butene-4-olid unsaturated lacton on the Η2Ο2 + ΗΟΟ- reaction rate has been studied . Taking into consideration the fact that the mentioned lacton is oilsoluble its water-ethanol solutions, as well micellar systems obtained making use two kinds of surfactants: C12H25SO−4Na+ and C12H25 N+(CH)3Cl−. It has been established that in lacton absence: 

− EtOH decreases the reaction rate (R), but in presence of lacton there is some increase in R value. This phenomenon is discussed in detail.

− In micellar systems the lacton action is similar. There is one difference. After some increase in micelles concentration the reaction rate in lacton presence becomes lower than the R value, determined in lacton absence. This regularity is also discussed in detail, as well as the RNO• action.

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Published

2010-02-24

Issue

Vol. 44 No. 1 (221) (2010)

Section

Chemistry

License

Copyright (c) 2010 Proceedings of the YSU

Creative Commons License

This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.

How to Cite

“THE ACTION OF UNSATURATED CYANOLACTON ON Η2Ο2+ΗΟΟ− REACTION RATE IN ABSENCE AND PRESENCE OF MICELLES”. 2010. Proceedings of the YSU B: Chemical and Biological Sciences 44 (1 (221): 12-17. https://doi.org/10.46991/PYSUB.2010.44.1.012.