STUDY OF THE KINETICS AND MECHANISM OF PHENYLDIETHANOLAMINE REACTION WITH POTASSIUM PERSULFATE. III. INFLUENCE OF MICELLES ON THE REACTION RATE

Authors

  • M. G. Gevorgian Chair of Physical and Colloids Chemistry, YSU, Armenia
  • N. M. Beylerian Chair of Physical and Colloids Chemistry, YSU, Armenia

DOI:

https://doi.org/10.46991/PYSUB.2002.36.2.068

Abstract

The influence of anionic and nonionic micelles on phenyldiethanolamine reaction with potassium persulfate in aqueous solutions at 298 K has been studied. It has been established that in presence of both type micelles the reaction rate, determined by iodometric and colorimetric methods decreases. With enhance of surfactants initial concentration the magnitude of the slowing – down of the reaction rate increases. On the basis of kinetic data the constants of amine binding with E-30 micelles have been calculated. It has been assumed that the first product of amine oxidation is localized in micelle hydrophobe nuclei.

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Published

2002-07-15

Issue

Vol. 36 No. 2 (198) (2002)

Section

Chemistry

License

Copyright (c) 2002 Proceedings of the YSU

Creative Commons License

This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.

How to Cite

“STUDY OF THE KINETICS AND MECHANISM OF PHENYLDIETHANOLAMINE REACTION WITH POTASSIUM PERSULFATE. III. INFLUENCE OF MICELLES ON THE REACTION RATE”. 2002. Proceedings of the YSU B: Chemical and Biological Sciences 36 (2 (198): 68-75. https://doi.org/10.46991/PYSUB.2002.36.2.068.

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