CATALYTIC ACTIVITY OF THE COBALT(II) ION WITH PHENYLALANINE COMPLEX IN THE DECOMPOSITION REACTION OF CUMENE HYDROPEROXIDE IN AQUEOUS SOLUTION

Authors

  • G.S. Grigoryan Chair of Physical and Colloids Chemistry, YSU, Armenia

DOI:

https://doi.org/10.46991/PYSU:B/2020.54.2.105

Keywords:

cobalt(II) ion, amino acid, phenylalanine, cumene hydroperoxide, complex, catalytic decay, kinetics

Abstract

The formation of Cօ2+ : phenylalanine (Phe) 1:1 complex has been confirmed via kinetic study in aqueous solution at pH>7, which acts as a model catalyst for the decomposition of cumene hydroperoxide (ROOH) in Co2++Phe+ROOH+H2O system. The kinetic expression of a single catalytic decomposition reaction of ROOH under the influence of [CoPhe]+ complex, as well as the Arrhenius equation describing the temperature dependence of the effective constant Keff (=Kcat[Co2+]0[Phe]0) of ROOH decay rate in the temperature range from 323 to 343 K are brought out.

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Published

2020-08-17

How to Cite

Grigoryan, G.S. 2020. “CATALYTIC ACTIVITY OF THE COBALT(II) ION WITH PHENYLALANINE COMPLEX IN THE DECOMPOSITION REACTION OF CUMENE HYDROPEROXIDE IN AQUEOUS SOLUTION”. Proceedings of the YSU B: Chemical and Biological Sciences 54 (2 (252):105-11. https://doi.org/10.46991/PYSU:B/2020.54.2.105.

Issue

Vol. 54 No. 2 (252) (2020)

Section

Chemistry

License

Copyright (c) 2020 Proceedings of the YSU

Creative Commons License

This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.

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