SYNTHESIS OF NEW CHIRAL Ni(II) COMPLEXES OF SCHIFF’S BASE OF DEHYDROALANINE

Authors

  • H. H. Hambardzumyan YSU, Armenia
  • A. S. Saghiyan YSU, Armenia
  • A. A. Petrosyan YSU, Armenia
  • L. L. Manasyan YSU, Armenia
  • G. M. Mkrtchyan YSU, Armenia
  • A. A. Avetisyan YSU, Armenia
  • V. I. Maleev Nesmeyanov Institute of Organoelement Compounds, RF
  • Yu. N. Belokon' Nesmeyanov Institute of Organoelement Compounds, RF

DOI:

https://doi.org/10.46991/PYSUB.2004.38.3.075

Keywords:

S)-N-(2-benzoylphenyl)-l-(3,4-dichlorbenzyl)pirrolydin-2-carboxamide, (S)-N-(2-(2',5'-dimethylphenyl)benzoyl)-1-benzylpirrolydin-2-carboxamide, Schifts bases, atropoisomers

Abstract

New methods for the synthesis of the chiral reagents (S)-N-(2-benzoylphenyl)-l-(3,4-dichlorbenzyl)pirrolydin-2-carboxamide (CPB) and (S)-N-(2-(2',5'-dimethylphenyl)benzoyl)-1-benzylpirrolydin-2-carboxamide (BBX) and their chiral Ni2+ complexes of Schifts bases with dehydroalanine (Ni-CPB-Δ-Ala and Ni-BBX-Δ-Ala) has been elaborated. All the complexes derived from BBX are formed as atropoisomers. These atropoisomers were isolated and subjected to spectral analysis.

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Published

2004-10-19

Issue

Vol. 38 No. 3 (205) (2004)

Section

Chemistry

License

Copyright (c) 2004 Proceedings of the YSU

Creative Commons License

This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.

How to Cite

“SYNTHESIS OF NEW CHIRAL Ni(II) COMPLEXES OF SCHIFF’S BASE OF DEHYDROALANINE”. 2004. Proceedings of the YSU B: Chemical and Biological Sciences 38 (3 (205): 75-84. https://doi.org/10.46991/PYSUB.2004.38.3.075.

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